功能化 Zr

基于UiO的金属有机框架（MOF）在锆MOF大家族中引起了许多科学家的关注。UiO 系列包括 UiO-66、-67 和 -68，具有高稳定性、可调性、孔隙率和功能，自 2008 年以来正在迅速扩展金属有机框架领域。连接器被功能化并导致产生具有所需特性和应用的新结晶材料。本综述在结构分类方面全面介绍了所有已报告的功能化和非功能化 UiO-67 MOF。UiO 基 MOF 的整体框架由三种不同的接头构建，包括 4,4'-联苯二羧酸 (bpdc)、2,2'-联吡啶-5,5'-二羧酸 (bipydc) 和 2-苯基吡啶-5，4'-二羧酸（ppydc）。此外，还研究了 MOF 内这些接头的金属化。此外，还对基于 UiO-67 的 MOF 的应用进行了简要研究。

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UiO based metal-organic frameworks (MOFs) have attracted much attention of many scientists among the large family of Zirconium MOFs. UiO-series including UiO-66, -67 and -68 which possesses high stability, tunability, porosity, and functions, are rapidly extending field in metal-organic frameworks since 2008. This progress in this family of MOFs, extended to the ability of linkers to be functionalized and led to generate new crystalline materials with desired properties and applications. This review presents comprehensively all of the reported functionalized and unfunctionalized UiO-67 MOFs in terms of structural classification. The overall framework of UiO- based MOF constructed from three different linkers including 4,4′-biphenyl dicarboxylic acid (bpdc), 2,2′-bipyridine-5,5′-dicarboxylic acid (bipydc) and 2-phenylpyridine-5,4′-dicarboxylic acid (ppydc). Also, the metalation of these linkers within MOFs investigated. Furthermore, a brief study on the application of the UiO-67-based MOFs was conducted.