轻钢笔记《ALC/AAC的历史》

蒸压加气混凝土(AAC)是一种很受欢迎的建筑材料，它的历史可以追溯到20世纪早期。在其存在期间，AAC在国际建筑市场上获得了相当大的份额，今天，它仍然保持着作为未来建筑材料的声誉。这篇综述介绍了AAC的发现、早期的商业开发和最终的国际成功的背景。在此描述了不同的AAC制造技术，以及多年来竞争是如何促进AAC制造方法的。由于持续创新，AAC的最新发展概况将以展望AAC行业前景结束。

Early History

AAC as a building material has been industrially produced since the beginning of 20th century. AAC stands for Autoclaved Aerated Concrete, alternatively known as Aerated Cellular Concrete (ACC) or Autoclaved Lightweight Concrete (ALC). Early history of AAC is based on a series of process patents.

AAC是20世纪初开始工业化生产的建筑材料。AAC是蒸压加气混凝土的简称，也被称为加气泡沫混凝土(ACC)或蒸压加气轻质混凝土(ALC)。AAC的早期历史是基于一系列的工艺专利。

In 1880, a German researcher, Michaelis was granted a patent on his steam curing processes. Czech Hoffman successfully tested and patented the method of “aerating” the concrete by carbon dioxide in 1889. Americans Aylsworth and Dyer used aluminium powder and calcium hydroxide to attain porous cementitious mixture for which they also received a patent in 1914. Swede Axel Eriksson made a serious next step towards developing modern AAC, when in 1920m he patented the methods of making aerated mix of limestone and ground slate; so-called the “lime formula”.

1880年，一位名叫米切里斯的德国研究人员获得了蒸汽固化工艺的专利。1889年，捷克人霍夫曼成功地测试并申请了二氧化碳“充气”混凝土的专利。美国人艾尔斯沃斯和戴尔使用铝粉和氢氧化钙制成多孔胶凝混合物，并于1914年获得专利。瑞典人阿克塞尔•埃里克森(Axel Eriksson)在开发现代AAC方面迈出了严肃的下一步。1920年，他申请了制造掺有石灰石和地石板的充气混合物的专利;所谓的“石灰配方”。

Chemistry

The combination of cement, lime, gypsum (anhydrite),finely ground sand and most importantly aluminium powder causes the mixture to expand considerably.From the beginning to the end the simplified chemical reactions are shown in fig. 1, which is the final Tobermorite or Hydrated Calcium Silicate C5S6H5.

水泥、石灰、石膏(硬石膏)、细砂和最重要的铝粉的混合物会使混合物膨胀。从开始到结束的简化化学反应如图1所示，这是最终的托贝morite或水合硅酸钙C5S6H5。

The Breakthrough

The real breakthrough in the masonry industry camein 1923 when the same architect Axel Eriksson dis-covered that this moist foamed mass can easily han-dle pressurized steam curing process, also known asautoclaving. While applying for a patent, two crucialconclusions were drawn: 1. the material hardenedfast thanks to the autoclaving process 2. shrinkagewas almost absent after steam curing compared tothe normal air curing. Additionally, it was also discov-ered that alternative materials, such as pulverizedash, could be used instead of lime/cement, allowingto economize on expensive raw material binder.

1923年，同一名建筑师阿克塞尔·埃里克森(Axel Eriksson)提出，这种潮湿的泡沫体可以很容易地进行加压蒸汽养护，也称为高压蒸汽养护，这是砌体工业的真正突破。在申请专利的过程中，得出了两个重要的结论:1。由于采用了高压灭菌法，这种材料硬化得很快。与普通空气养护相比，蒸汽养护几乎不存在收缩。此外，还发现可以用其它材料，如粉煤灰，来代替石灰/水泥，从而节省昂贵的原材料粘合剂。

Start of Commercial Manufacturing

Eriksson’s success immediately attracted a much-needed commercial interest and in 1929 the first large scale manufacturing facility of these artificially-made crystalized stone blocks was launched in a factory named “Yxhults Stenhuggeri Aktibolag” in Sweden under the name Yxhult (fig. 2 & 3). In 1940,the Yxhult name was changed to Ytong as this name was easier to pronounce. In 1932, the factory Carlsro Kalkbruk Skovde started with AAC block production and the product acquired the brand name Durox. An important competitor arose in 1934, which started to manufacture AAC blocks under the brand name Siporit and renamed as Siporex as of 1937. Siporex was also the first to introduce the AAC reinforced elements in 1935, namely roof, floor panels and lintels.Good structural properties of the newly created AAC material soon spread all over Western Europe, with more than six plants only in Sweden alone.

埃里克森的成功立即吸引了一个急需的商业兴趣，并于1929年在瑞典一个名为Yxhult的名为Yxhults Stenhuggeri Aktibolag的工厂里建立了第一个大规模的人造水晶砌块生产设施(图2和图2;1940年，Yxhult的名字改为Ytong，因为Ytong更容易发音。1932年，卡尔斯罗·卡尔克布鲁克·斯可夫德(Carlsro Kalkbruk Skovde)开始生产AAC块，该产品获得了品牌Durox。1934年，一个重要的竞争对手出现了，它开始以Siporit品牌生产AAC积木，并于1937年改名为Siporex。Siporex也是1935年第一个引入AAC加固元素的公司，即屋顶、地板和楣板。新发明的AAC材料良好的结构性能很快就传遍了西欧，仅在瑞典就有六家以上的工厂。

Different Technologies –International Success

AAC manufacturing went international in 1937 with introduction of technology licensing and know-how transfer. After World War II, there existed only a few leading AAC technology suppliers: Siporex and Ytong (both belonging to the Swedes), Durox (bought by the Dutch) and Hebel (German). Throughout the 20th century, all of them successfully sold AAC technology licenses around the world, while at the same time annual conventions contributed to further developments in AAC production, product quality and its applications.Among different manufacturing technologies, production of AAC blocks became associated with Ytong (tilt-cake system), while production of both AAC blocks and reinforced elements was led by Durox, Siporex and later on, Hebel with flat-cake systems.

1937年，随着引进技术许可和技术转让，AAC制造走向国际。第二次世界大战后，只有几家领先的AAC技术供应商:Siporex和Ytong(都属于瑞典人)、Durox(被荷兰人收购)和Hebel(德国人)。在整个20世纪，他们都成功地在世界各地销售了AAC技术许可证，同时，年度大会促进了AAC生产、产品质量和应用的进一步发展。在不同的制造技术中，AAC砌块的生产与Ytong(倾饼系统)联系在一起，而AAC砌块和增强元件的生产由Durox、Siporex和后来的Hebel(平饼系统)领导。

Competition and Growth

Germany, United Kingdom, Sweden, Denmark and theNetherlands established themselves as the main AAChubs after WWII, albeit the fact that countries useddifferent technologies to produce similar products.Following the triumph of AAC material on an international arena, competition grew stronger between theparties in that relatively small market, often endingup in a battle of patents. Slowly in the 1980s, theinfluence of Swedes was diminished due to the suffering domestic market. As a result, Siporex activitieswere reduced to a minimum level and no new plantswere built since the 1990s. Additionally, duringthe 1980s, Germans took over and improved on theknow-how of Ytong from the Swedes. Despite fiercecompetition, multiple plants were realized in Asia,Middle East and Eastern Europe, based on all fourdifferent technologies. In the beginning of the 1990s,the first AAC plant based on a tilt-cake technology(Ytong) was supplied to China. From that point onwards, technology outflow became widespread andas of 2014, there are more than 3,000 AAC productionfacilities worldwide with an estimated production capacity of 450 million m3 per year of non-reinforcedblocks. Mass production of blocks is also popularin Central and Eastern Europe and India while Japanese, Korean, Australian and Western Europeanmarkets are focusing more and more on reinforcedpanels and high precision blocks.

德国、英国、瑞典、丹麦和荷兰在二战后成为了主要的AAC中心，尽管这些国家使用不同的技术生产相似的产品。随着AAC材料在国际舞台上的胜利，在这个相对较小的市场中，各方之间的竞争越来越激烈，常常以专利之争告终。20世纪80年代，由于国内市场不景气，瑞典人的影响力逐渐减弱。结果，Siporex的活动减少到最低水平，自1990年代以来没有新建工厂。此外，在20世纪80年代，德国人从瑞典人手中接管并改进了Ytong的技术。尽管竞争激烈，在亚洲、中东和东欧建立了多家工厂，采用了四种不同的技术。上世纪90年代初，美国第一家采用倾斜蛋糕技术(Ytong)的AAC工厂被供应给中国。从那以后，技术外流变得很普遍，到2014年，全世界有超过3000个AAC生产设施，估计每年生产4.5亿立方米的非加固砌块。砌块的大规模生产在中欧、东欧和印度也很受欢迎，而日本、韩国、澳大利亚和西欧市场正越来越多地关注加强面板和高精度砌块。

Reinforced Elements

Short after the first AAC block plant emerged in Sweden in 1929, structural reinforced elements followed.Siporex posed a strong competition to Eriksson’s AAC process technology when first reinforced roof and floor panels were successfully manufactured in Sweden, with a so-called “cement formula”. It used mainly cement instead of lime as a binder, which improved the process properties as well as structural load bearing characteristics. The main goal of the Siporex products was to design a complete building system using only AAC. A decade later, Hebel technology evolved in the mid-1940s under the patronage of German engineer Josef Hebel.

不久之后，第一个AAC块工厂出现在1929年瑞典，结构加强元素随后。当瑞典首次成功地使用所谓的水泥配方生产加固屋顶和地板时，Siporex对埃里克森的AAC工艺技术构成了强有力的竞争。主要采用水泥代替石灰作为粘结剂，改善了工艺性能和结构承载性能。Siporex产品的主要目标是设计一个只使用AAC的完整建筑系统。十年后，在德国工程师约瑟夫·赫贝尔的资助下，赫贝尔技术在20世纪40年代中期得到了发展。

After studying the plant in the Baltics during the WWII, Josef Basel based his production technology on Siporex and managed to bring remarkable improvements to the AAC production technology, especially to the reinforced products. Given the disappearance of Siporex from the market, Durox and Hebel technologies became leaders in supplying the reinforced AAC elements due to their more suitable and favourable cutting and curing technique (fig. 4).

在研究了二战期间波罗的海国家的工厂后，约瑟夫·巴塞尔(Josef Basel)将他的生产技术基于Siporex，并成功地将AAC的生产技术，尤其是增强产品进行了显著的改进。Siporex从市场上消失后，Durox和Hebel technologies由于其更合适和更有利的切割和固化技术，成为AAC增强元件供应的领导者(图4)。

In Eastern and Western Europe, many AAC plants successfully supply both AAC blocks and AAC panels. Japan until today, remains a 100% reinforced elements market (fig. 5). Since 2002, reinforced element production was further perfected by the Dutch and nowadays Aircrete Europe’s technology allows manufacturing complete prefab AAC building solutions. Taking into consideration fast, economic and structural building with AAC panels, many countries today are looking for ways to introduce complete AAC building solutions in their local construction markets.

在东欧和西欧，许多AAC工厂成功地提供了AAC模块和AAC面板。直到今天，日本仍然是一个100%增强元件市场(图5)。自2002年以来，荷兰进一步完善了增强元件的生产，如今Aircrete欧洲公司的技术允许制造完整的预制AAC建筑解决方案。考虑到快速、经济和结构建筑与AAC面板，许多国家今天正在寻找方法，以介绍完整的AAC建设解决方案在其当地建筑市场。

Mergers & Acquisitions

Mergers and acquisitions wave of the 1990s has had a crucial impact on the world of AAC as we know it today. In the period between early 1990s and early 2000s, ownership of technologies, plants and brand names became disoriented. Plants, patents, technologies and patents of Durox, Ytong and Hebel ended up under one roof and named Xella. At one point,Hebel and Durox products were produced under the brand name Ytong, as all three brand names were unified under the name Ytong. In 2001, a range of factories were closed under the premise of overcapacity.Many AAC technology specialists lost their jobs. Hebel took the biggest hit as their main base in Emmering, Germany was closed, and some Hebel facilities were liquidated, stating that production costs became too high. The market of architects, builders and especially the end consumers could not understand the disappearance of the well-known brands. Following this, the brand “Hebel” was reinstated as a brand for the reinforced products, while Ytong remained a brand for blocks. Furthermore, not a single Durox plant was closed throughout AAC’s history and AAC is produced until now in the remaining plants as well as the original Durox based plants.The period was an exodus of know-how in AAC world and many licensees had to fi nd their own way in the world of AAC.

上世纪90年代的并购浪潮对我们今天所熟知的AAC行业产生了至关重要的影响。在20世纪90年代初至21世纪初，技术、工厂和品牌的所有权变得混乱。Durox、Ytong和Hebel的植物、专利、技术和专利被集中在一个屋檐下，命名为Xella。Hebel和Durox的产品一度以Ytong品牌生产，因为这三个品牌都统一在Ytong名下。2001年，在产能过剩的前提下，许多工厂被关闭。许多AAC技术专家失去了工作。赫贝尔受到的打击最大，因为他们的主要基地在埃默林，德国被关闭，一些赫贝尔的设施被清算，声称生产成本变得太高。建筑师、建筑商，尤其是终端消费者无法理解知名品牌的消失。随后，“赫贝尔”品牌被恢复为加固产品的品牌，而“逸通”则保留了几个街区的品牌。此外，在整个AAC的历史中，没有一家Durox工厂被关闭，直到现在，在剩余的工厂和最初的Durox工厂都生产AAC。这一时期AAC领域的技术人才大量流失，许多获得执照的人不得不在AAC领域找到自己的路。

AAC Machine Builders

During the aforementioned period, market forces changed considerably shifting the focus away from technology and processes to machines and pricing.The machine builders, mainly from Europe and later China, entered the open space in the market. Ytong technology and its various tilt-cake derivations were picked up by machine building companies and sold as “own technology” AAC equipment. The focus of the industry went from technology supply and assistance to machine supply and after-sales. Autoclaved aerated concrete world market became fragmented as knowledge sharing about production technology,product application and latest developments was not promoted anymore. Machine builders - generally - do not own AAC production facilities and therefore rely only on their customers when it comes to AAC product,application, chemical processes, etc. Additionally,fi nancial participation of technology suppliers in their own factories was not uncommon in the past.Hence, the gap between the architects, contractors,factories and machine builders is wider today than it used to be, forcing every AAC producer to solve the same industry issues on their own.

在上述期间，市场力量发生了巨大的变化，将重点从技术和过程转移到机器和定价。机器制造商，主要来自欧洲和后来的中国，进入了市场的开放空间。Ytong technology及其各种倾斜蛋糕衍生产品被机械制造公司收购，并作为自有技术AAC设备出售。该行业的重点从技术供应和协助转向了机器供应和售后服务。随着生产技术、产品应用、最新发展等方面的知识共享不再推进，蒸压加气混凝土的世界市场变得支离破碎。机械制造商通常不拥有AAC生产设施，因此在涉及AAC产品、应用、化学过程等时，他们只依赖客户。此外，技术供应商在他们自己的工厂里的财务参与在过去并不少见。因此，建筑师、承包商、工厂和机械制造商之间的差距比以往更大，迫使每一家AAC制造商自己解决相同的行业问题。

AAC Products Today

The technology of AAC production has developed signifi cantly over the last decades. Production of ordinary non-reinforced AAC blocks is not linked to any exclusive know-how anymore and as a result, AAC blocks became a commodity in many markets. Manufacturing light and heavy reinforced AAC elements is still a big challenge for most of the producers in the world, primarily with tilt-cake technologies. Nevertheless,in time, physical properties of AAC material improved and applications became more universal from the construction point of view. Today, AAC is a structural solid building material, an excellent thermal insulator, a good sound absorber and an attractive decoration material. Certain technology professionals are able to produce products with density range from 300-800 kg/m3. Nowadays, lambda values of 0.08 (thermal conductivity) at a density of 300 kg/m3 is not an exception anymore. Additionally, compliance with strict EU standards (EN 771-4 and EN 772-16) results in high-precision products (tolerances of